导师信息
姓 名:刘昆明
性 别:男
学位/职称:博士/副教授
出生年月:1985.03
联系方式:18720896810
电子邮箱:liukunming@jxust.edu.cn
办公地点:稀土大楼B511(办公室)/B707(实验室)
学科专业:化学工程与技术、应用化学
讲授课程:有机化学、有机合成、高分子化学、分析化学
研究方向:有机合成方法学、功能有机小分子及高分子材料的制备
出版著作及代表性论文:
(1) Dandan Jiang, Minghao Zheng, Xiaofan Ma Yingzhen Zhang, Shaohua Jiang, Juanhua Li, Chunmei Zhang, Kunming Liu*, Liqing Li*. Rhodamine-Anchored Polyacrylamide Hydrogel for Fluorescent Naked-Eye Sensing of Fe3+. Molecules 2023, 28, 6572.
(2) Yingliang Feng, Lihua Zhu*, An Pei, Sifan Zhang, Kunming Liu*, Fengshun Wu, Wenqi Li. Platinum-palladium-on-reduced graphene oxide as bifunctional electrocatalysts for highly active and stable hydrogen evolution and methanol oxidation reaction. Nanoscale, 2023, 15, 16904-16913.
(3) Gao Liang, Zheng Minghao, Liu Haiyi, Xiao Jun, Gong Tianhao, Liu Kunming*, Li Juanhua*, Liu Jinbiao*. A novel HBI-based ratiometric fluorescent probe for rapid detection of trifluoroborate. RSC Adv., 2023, 13, 23812.
(4) Ying Wang, Huilin Xie, Kunming Liu *, Jinhui Li *, Jin-Biao Liu *. Selective C-O Coupling Reaction of N-Methoxy Arylamides and Arylboronic Acids Catalyzed by Copper Salt. Catalysts 2022, 12, 1278.
(5) Liqing Li, Minghao Zheng, Xiaoyang Yan, Hui Huang, Shuxin Cao, Kunming Liu*, Jin-Biao Liu*. Quantitative detection of H2O2 with a composite ffuorescent probe of 8-quinoline boronic acid-Al(III). J. Photoch. Photobio., A Chem. 2022, 432, 114069.
(6) Dandan Jiang, Minghao Zheng, Xiaoyang Yan, Bin Huang, Hui Huang, Tianhao Gong, Kunming Liu*, Jinbiao Liu*. A “turn-on” ESIPT fluorescence probe of 2- (aminocarbonyl)phenylboronic acid for the selective detection of Cu(II). RSC Adv., 2022, 12, 31186.
(7) Pinyong Zhong, Jiajia Wu, Junran Wu, Kunming Liu*, Changfeng Wan*, Jin-Biao Liu*. Solvent-controlled selective synthesis of amides and thioureas from isothiocyanates. Tetrahedron Lett. 2022, 107, 154099.
(8) Liqing Li,Minghao Zheng,Dandan Jiang,Shuxin Cao,Kunming Liu*,Jinbiao Liu*. Colorimetric and Fluorescent Probes Based on the Oxidation of o-Phenylenediamine for the Detection of Bio-Molecules. Prog. Chem., 2022, 34, 1815-1830.
(9) Qiuxiang Ye, Shangfeng Ren, Hui Huang, Gaigai Duan, Kunming Liu,* Jin-Biao Liu*. Fluorescent and Colorimetric Sensors Based on the Oxidation of o-Phenylenediamine. ACS Omega 2020, 5, 20698−20706.
(10) Shangfeng Ren, Nianhua Luo, Kunming Liu*, Jin-Biao Liu*. Synthesis of unsymmetrical disulfides via the cross-dehydrogenation of thiols. J. Chem. Res. 2020, 1-9.
(11) 黄辉, 李娟华, 吴广东, 黄琦, 刘昆明*. 硬段类型和含量对嵌段聚氨酯脲性能的影响. 高分子材料科学与工程. 2020. 36, 63-69.
(12) Di Wang, Jiajun Yu, Gaigai Duan,* Kunming Liu, Haoqing Hou*.Electrospun polyimide nonwovens with enhanced mechanical and thermal properties by addition of trace plasticizer. J Mater Sci, 2020, 55, 5667–5679.
(6) Lichen Xu, Kunming Liu, Xinfang Duan*. Iron-Catalyzed Room Temperature Cross-Couplings of Bromophenols with Aryl Grignard Reagents. Adv. Synth. Catal. 2019, 361, 1 –8.(并列一作)
(7) Hui Huang, Juanhua Li, Kunming Liu*, Jinbiao Liu. Recent Progress in Transition Metal-Catalyzed Coupling Reactions of Organotitanium Reagents. Chin. J. Org. Chem. 2019, 39, 1293-1301.
(8) Yulin Wang, Qingli Qu, Shuting Gao, Guosheng Tang, Kunming Liu, Shuijian He, Chaobo Huang* . Biomass derived carbon as binder-free electrode materials for supercapacitors. Carbon 2019, 155, 706-726.
(9) Rui Zhang, Yan Zhao, Kunming Liu, Xinfang Duan* . Phenolate Enabled General and Selective Fe/Ti Cocatalyzed Biaryl Cross-Couplings between Aryl Halides and Aryl Grignard Reagents. Org. Lett. 2018, 20, 7942-7946.
(10) Juan Wei, Kunming Liu, Xinfang Duan*.Cobalt-Catalyzed Biaryl Couplings via C−F Bond Activation in the Absence of Phosphine or NHC Ligands. J. Org. Chem. 2017, 82, 1291−1300.
(11) Juanhua Li, Kunming Liu*, Xinfang Duan, Jinbiao Liu. Recent Progress in Iron Catalyzed C-C coupling Reactions. Chin. J. Org. Chem. 2017, 37, 314-344.
(12) Kunming Liu, Rui Zhang, Xinfang Duan*. Room-temperature cobalt-catalyzed arylation of aromatic acids: overriding the ortho-selectivity via the oxidative assembly of carboxylate and aryl titanate reagents using oxygen, Org. Biomol. Chem., 2016, 14, 1593-1598.
(13) Kunming Liu, Juan Wei, Xinfang Duan* . Iron-catalyzed oxidative biaryl cross-couplings via mixed diaryl titanates: significant influence of the order of combining aryl Grignard reagents with titanate. Chem. Commun., 2015, 51(22): 4655-4658.
(14) Kunming Liu, Lianyan Liao, Xinfang Duan* . Iron Catalyzed Oxidative Assembly of N-heteroaryl and Aryl Metal Reagents Using Oxygen as an Oxidant. Chem. Commun., 2015, 51(6): 1124-1127.
(15) Lianyan Liao, Kunming Liu, Xinfang Duan* . Unified Protocol for Cobalt-Catalyzed Oxidative Assembly of Two Aryl Metal Reagents Using Oxygen as an Oxidant. J. Org. Chem. 2015, 80(20): 9856-9867.
(16) Kunming Liu, Fang Zhang, Xinfang Duan*. 1, 2-Addition of Alkyl Grignard Reagents to the Nitro Group: Simple Access to 2- [Alkyl (hydroxy) amino] pyridine N-Oxides and 2-Alkylaminopyridine N-Oxides. Eur. J. Org. Chem., 2013, 27, 6152-6157.
(17) Jing Zeng, Kunming Liu, Xinfang Duan*. Selective Co/Ti Cooperatively Catalyzed Biaryl Couplings of Aryl Halides with Aryl Metal Reagents. Org. Lett., 2013, 15(20): 5342-5345.
主持承担科研项目及经费:
(1)江西省自然科学面上基金,基于动态络合平衡的新型ate-络合物参与的铁催化偶联反应研究(20212BAB203013),在研,10万,主持。
(2)江西省自然科学基金青年项目,五(六)元环醚的多组分开环及串联反应研究(20202BABL213007),结题,6万,主持。
(3)赣州市创新领军人才项目,基于动态配位的稀土-聚合物力致变色荧光材料研究(赣市科发[2020]号),结题,主持。
(4)江西省教育厅科技项目, 铁催化脱羧-环化串联反应合成多取代杂环化合物研究(GJJ160668),结题,2万,主持。
(5)江西理工大学博士启动基金项目,新型钛试剂的设计、制备及应用,结题,3万,主持。
(6)国家自然科学基金地区项目,重氮介导的芳甲基骨架多官能团化反应研究(21762018),结题,38万,主要参与人。
(7)国家自然科学基金面上项目,铁钴催化的有机钛试剂协同型偶联反应的研究,结题,80万(21372031),参与。
授权专利:
(1)刘昆明 刘晋彪 黄辉 李娟华,一种苯并噁唑类荧光探针及制备方法及应用,ZL202010806160.0。
(2)刘昆明,刘晋彪,王瑞祥,李立清,李娟华,一种镨离子荧光探针化合物、其制备方法及应用,ZL202110543135.2。