导师信息

姓 名：刘昆明

性 别：男

学位/职称：博士/副教授

出生年月：1985.03

联系方式：18720896810

电子邮箱：liukunming@jxust.edu.cn

办公地点：稀土大楼B511（办公室）/B707（实验室）

学科专业：化学工程与技术、应用化学

讲授课程：有机化学、有机合成、高分子化学、分析化学

研究方向：有机合成、荧光探针、功能高分子

近5年出版著作及代表性论文：

1. Jiang, D. D.; Xiao, J.; Zou, L.-X.; Qiao, X.; Zhao, H. L.; Liu, K. M.*; Li, J.-H.*; Wen, H. R.* Iron-catalyzed direct N-methylation of N-methoxy benzamides: A solvent-free approach to bisamides utilizing the methoxy group as a “build-in” methylene donor. J. Mol. Struct. 2025, 1330, 141472.

2. Xiao, J.; Jiang, D. D.; Wu, X. J.; Li, J. H.; Liu, K. M.*; Huang, B.*; Wang, W.* Carbene-induced ring-opening reactions of five-/six-membered cyclic ethers: expanding the frontiers of functional group introduction and molecular architecture construction. Org. Biomol. Chem. 2025, 23, 2024–2040.

3. Zhang, Y. Z.; Liu, J.; Xiao, J.; Li, F.; Liu, K. M.*; Yang, M.*; Liu, J. B.* A PET based colorimetric/fluorescent dual-signal probe for selective detection of hypochlorite in real water samples. J. Mol. Struct. 2025, 1322, 140568.

4. Luo, Y. Y.; Zheng, S. Y.; Yu, H. J.; Dong, C. C.; Liu, K. M.*; Li, J. H.*; Liu, J. B.* Synthesis of a dual-response signal sensor and naked-eye recognition of hypochlorite in real water sample. J. Mol. Struct. 2025, 1320 ,139652.

5. Zhang, Y. Z.; Xiao, J.; Peng, R. Y.; Feng, X. L.; Hao, H. M.; Liu, K. M.*; Liu, Z. Z.*; Ma, C. X*. Benzo[1,2-b:6,5-b’]Dithiophene-4,5-Diamine: A New Fluorescent Probe for the High-Sensitivity and Real-Time Visual Monitoring of Phosgene. Sensors 2025, 25, 407

6. Zhong, P. Y.; Yang, M.; Liu, K. M.; He, W. M.; Liu, J. B.* Visible-light-driven method for the selective synthesis of amides and N-acylureas from carboxylic acids and thioureas. Chem. Eur. J. 2024, e202402677.

7. Duan, L. L.; Zhong, P. Y.; Liu, J. B.*; Liu, K. M.*; Luo, N. H.* Photocatalytic synthesis of (un)symmetrical ureas and benzimidazolones from amines and CS₂. Mol. Catal. 2024, 546, 114344.

8. Jiang, D. D.; Zhang, Y. Z.; Qiao, X.; Xiao, J.; Liu, K. M.*; Li, J.-H.*; Liu, J. B.* Selective N=S coupling reactions of N-methoxy arylamides and sulfoxides catalyzed by iron salt. ACS Omega 2024, 9, 37044−37051.

9. Zhang, Y. Z.; Jiang, D. D.; Li, J. H.; Wang, J. J.; Liu, K. M.*; Liu, J. B.* Construction strategy and imaging of highly selective selenocysteine fluorescent probes. Chin. J. Org. Chem. 2024, 44, 41−53.

10. Jiang, D. D.; Zheng, M. H.; Ma, X. F.; Zhang, Y. Z.; Jiang, S. H.; Li, J. H.; Zhang, C. M.; Liu, K. M.*; Li, L. Q.* Rhodamine-anchored polyacrylamide hydrogel for fluorescent naked-eye sensing of Fe³⁺. Molecules 2023, 28, 6572.

11. Feng, Y. L.; Zhu, L. H.*; Pei, A.; Zhang, S. F.; Liu, K. M.*; Wu, F. S.; Li, W. Q. Platinum-palladium-on-reduced graphene oxide as bifunctional electrocatalysts for highly active and stable hydrogen evolution and methanol oxidation reaction. Nanoscale 2023, 15, 16904−16913.

12. Gao, L.; Zheng, M. H.; Liu, H. Y.; Xiao, J.; Gong, T. H.; Liu, K. M.*; Li, J. H.*; Liu, J. B.* A novel HBl-based ratiometric fluorescent probe for rapid detection of trifluoroborate. RSC Adv. 2023, 13, 23812.

13. Li, L. Q.; Zhong, X. M.; Zhang, L. X.; Liu, K. M.*; Wang, Q. B; Ma, J.* Preparation of Double Network Hydrogels and their Mechanical Modification. Prog. Chem. 2023, 35, 1674−1685.

14. Wang, Y.; Xie, H. L.; Liu, K. M.*; Li, J. H.*; Liu, J. B.* Selective C-O coupling reaction of N-methoxy arylamides and arylboronic acids catalyzed by copper salt. Catalysts 2022, 12, 1278.

15. Li, L. Q.; Zheng, M. H.; Yan, X. Y.; Huang, H.; Cao, S. X.; Liu, K. M.*; Liu, J. B.* Quantitative detection of H₂O₂ with a composite fluorescent probe of 8-quinoline boronic acid-Al(III). J. Photoch. Photobio. A Chem. 2022, 432, 114069.

16. Jiang, D. D.; Zheng, M. H.; Yan, X. Y.; Huang, B.; Huang, H.; Gong, T. H.; Liu, K. M.*; Liu, J. B.* A "turn-on" ESIPT fluorescence probe of 2-(aminocarbonyl)phenylboronic acid for the selective detection of Cu(II). RSC Adv. 2022, 12, 31186−31191.

17. Zhong, P. Y.; Wu, J. J.; Wu, J. R.; Liu, K. M.*; Wan, C. F.*; Liu, J.-B.* Solvent-controlled selective synthesis of amides and thioureas from isothiocyanates. Tetrahedron Lett. 2022, 107, 154099.

18. Li, L. Q.; Zheng, M. H.; Jiang, D. D.; Cao, S. X.; Liu, K. M.*; Liu, J. B.* Colorimetric and fluorescent probes based on the oxidation of o-phenylenediamine for the detection of bio-molecules. Prog. Chem. 2022, 34, 1815−1830.

19. Ye, Q. X.; Ren, S. F.; Huang, H.; Duan, G. G.; Liu, K. M.*; Liu, J.-B.* Fluorescent and colorimetric sensors based on the oxidation of o-phenylenediamine. ACS Omega 2020, 5, 20698−20706.

20. Huang, H.; Li, J. H.; Wu, G. D.; Huang, Q.; Liu, K. M.* Effect of hard segment structure and content on properties of block polyurethane ureas. Polym. Mater. Sci. Eng. 2020, 36, 63−69.

21. 刘昆明，李娟华，陈内. 廉价金属催化有机钛酸根型络合物的偶联反应. 冶金工业出版社，2022.

    主持承担科研项目及经费：

    （1）抚州市揭榜挂帅项目，电子封装用APG改性环氧树脂及潜伏性固化剂研发，在研，300万，主持。

    （2）江西省重点实验室开放项目，压电驱动单电子转金属化历程的烷基硼偶联反应研究，在研，2万，主持。

    （3）江西省自然科学面上基金，基于动态络合平衡的新型ate-络合物参与的铁催化偶联反应研究（20212BAB203013），结题，10万，主持。

    （4）江西省自然科学基金青年项目，五（六）元环醚的多组分开环及串联反应研究（20202BABL213007），结题，6万，主持。

    （5）赣州市创新领军人才项目，基于动态配位的稀土-聚合物力致变色荧光材料研究（赣市科发[2020]号），结题，主持。

    （6）江西省教育厅科技项目, 铁催化脱羧-环化串联反应合成多取代杂环化合物研究（GJJ160668），结题，2万，主持。

     

    授权专利：

    （1）刘昆明，刘晋彪，黄辉，李娟华，一种苯并噁唑类荧光探针及制备方法及应用，ZL202010806160.0。

    （2）刘昆明，刘晋彪，王瑞祥，李立清，李娟华，一种镨离子荧光探针化合物、其制备方法及应用，ZL202110543135.2。